RECOVERY OF CESIUM FROM EPITHERMAL MINERAL …
The cesium alum may be recovered from the crystallizer slurry by a solid-liquid separation step. Cesium alum is water-soluble, so any washing of the alum is advantageously carried out so as to avoid re-solubilisation of the cesium alum. For example, in some embodiments, a minimal amount of washing may be carried out, and …
اقرأ أكثر
Cesium Recovery from the Taron Deposit Demonstrated
94.7 % extraction of Cesium after 4 hours of leaching at 90 C with 250 g/L H2SO4 and 20 % Solids; Recovery of 97.8 to 99.4% of the Cesium as a Cesium Aluminum Sulfate …
اقرأ أكثر
JPS6036335A
JPS6036335A JP59143427A JP14342784A JPS6036335A JP S6036335 A JPS6036335 A JP S6036335A JP 59143427 A JP59143427 A JP 59143427A JP 14342784 A JP14342784 A JP 14342784A JP S6036335 A JPS6036335 A JP S6036335A Authority JP Japan Prior art keywords cesium permanganate alum solution reaction Prior art date …
اقرأ أكثر
Process for recovering cesium from cesium alum
@ Cesium is recovered from cesium alum, CsAl(SO4)2, by a two-reaction sequence in which the cesium alum is first dissolved in an aqueous hydroxide solution to form cesium alum hydroxide, CsAl (OH)3, and potassium sulfate, K2SO4. part of the K2SO4precipitates and is separated from the supernatant solution. In the second reaction, a water-soluble ...
اقرأ أكثر
Process for recovering cesium from cesium alum|INIS
Cesium is recovered from cesium alum, CsAl(SO 4 ) 2, by an aqueous conversion and precipitation reaction using a critical stoichiometric excess of a water-soluble …
اقرأ أكثر
Recovery of vanadium and cesium from spent …
Vanadium and cesium were recovered from spent sulfuric acid catalysts, generated during a sulfuric acid manufacturing process, by an environmentally friendly …
اقرأ أكثر
The Recovery of Cesium Salts from the Taron Deposit
The recovery of cesium has been studied using sulfuric acid leaching with recovery of cesium as alum. The waste solution from cesium recovery is oxidized and neutralized to form stable iron ...
اقرأ أكثر
Process for recovering cesium from cesium alum
Cesium is recovered from cesium alum, CsAl(SO4)2, by an aqueous conversion and precipitation reaction using a critical stoichiometric excess of a water-soluble permanganate to form solid cesium permanganate (CsMnO4) free from cesium alum. The other metal salts remain in solution, providing the final pH does not cause hydroxides of aluminum or …
اقرأ أكثر
Cesium Faq
Atomic number 55, Cesium is the heaviest of the natural alkali metals. Physically, it is a soft metal or light liquid, pale gold in color when pure, silvery-white otherwise. It melts at 28.4 C, just below body heat, and boils at 669.3 C. It has a specific gravity of 1.873, and an atomic weight of 132.9045.
اقرأ أكثر
The Recovery of Cesium Salts from the Taron deposit
The cesium alum is further treated to form high purity cesium hydroxide, which may be further processed to a range of cesium salts including cesium formate. The initial process developments for the Taron deposit are presented. ... The purified alum crystals were then recovered by filtration and drying. Washing was not applied in order to avoid ...
اقرأ أكثر
Cesium extraction from the Taron deposit
The process consists of acid leaching of the ground rock and separation of the barren leach residue from the leachate. Aluminum sulfate addition is used to promote selective precipitation of cesium alum from the leachate at low temperature. The …
اقرأ أكثر
A novel process for the selective precipitation of valuable …
The crystallization was aimed at the separation of rubidium and cesium from an acidic solution containing potassium as the main contaminant. The alum mixture contained on average 7.5% potassium, 1.3% rubidium and 0.30% cesium. The main crystalline components were aluminum sulfate and AlF(SO 4)·5H 2 O after concentration. …
اقرأ أكثر
Recovery of cesium chloride from pollucite ore
When sulfuric acid is used, the cesium may be recovered as cesium alum. Processes for further purification of cesium starting with cesium alum are described in U.S. Pat. Nos. 4,469,670 and 4,466,950. Alternatively, cesium ore may be roasted in admixture with an alkaline flux to convert the cesium to a water-soluble salt. For example, an ...
اقرأ أكثر
The Recovery of Cesium Salts from the Taron Deposit
The purified alum crystals were then recovered by filtration and drying. Washing was not applied in order to avoid alum re-dissolution. Cesium Hydroxide and Cesium Formate Production. A 2 g sample of the synthesized aluminum cesium sulfate crystals was fully dissolved in 100 mL of water held at 90 °C throughout the duration of …
اقرأ أكثر
The Recovery of Cesium Salts from the Taron Deposit
The recovery of cesium has been studied using sulfuric acid leaching with recovery of cesium as alum. The waste solution from cesium recovery is oxidized and …
اقرأ أكثر
Recovery of cesium from epithermal mineral deposits
[023] The cesium alum may be recovered from the crystallizer slurry by a solid- liquid separation step. Cesium alum is water-soluble, so any washing of the alum is advantageously carried out so as to avoid re-solubilisation of the cesium alum. For example, in some embodiments, a minimal amount of washing may be carried out, and …
اقرأ أكثر
US3489509A
cesium barium sulfate alum recovery Prior art date Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.) Expired - Lifetime Application number US639366A Inventor Irwin E Johnson
اقرأ أكثر
WO1996031435A1
The cesium alum is then redissolved in water at an elevated temperature and reacted with an alkaline earth metal hydroxide, such as barium hydroxide or calcium hydroxide, to form an aluminum hydroxide precipitate together with precipitated barium sulfate or calcium sulfate. ... The cesium can be recovered from the supernatant …
اقرأ أكثر
CESIUM ALUM AND ITS PROPERTIES. | Journal of the …
This article is cited by 4 publications. H. Ebert, Kl. Schäfer, G. Beggerow. Reine Stoffe in kondensierten Phasen.
اقرأ أكثر
Process for recovering cesium from cesium alum
Made available by U.S. Department of Energy Office of Scientific and Technical Information ...
اقرأ أكثر
5 PRODUCTION, IMPORT/EXPORT, USE, AND DISPOSAL
Cesium alum is crystallized from the leach filtrate by stage cooling to 50 °C and then to 20 °C and roasted in the presence of 4% carbon. The residue is leached to produce cesium sulfate solution, ... Radiocesium can be recovered from fission products by …
اقرأ أكثر
US4466950A
cesium permanganate solution hydroxide alum Prior art date Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.) Ceased Application number US06/512,926
اقرأ أكثر
Cesium extraction from the Taron deposit
Cascadero Copper Corp. has developed a hydrometallurgical process to recover cesium from mineral samples of the Taron deposit in Argentina. Cesium was …
اقرأ أكثر
SELECTIVE RECOVERY METHOD OF VANADIUM AND CESIUM …
Since cesium alum CsAl(SO 4) 2 recovered from the waste sulfuric acid vanadium catalyst may be directly utilized, or may be converted into the form of Cs 2 SO 4 through a smelting process including water leaching and then prepared into various compounds according to a purpose, the cesium alum CsAl(SO 4) 2 can be applied to various fields of ...
اقرأ أكثر
Process for recovering cesium from cesium ore
As already mentioned, where sulfuric acid is used for the digestion step, the cesium can be recovered as cesium alum, expressed as CsAl(SO 4) 2.12H 2 O or Cs 2 SO 4.Al 2 (SO 4) 3.24H 2 O. Where hydrobromic acid is used, the aluminum bromide can be removed first by isopropyl alcohol extraction, and the mixed alkali metal bromides recovered and ...
اقرأ أكثر
Cesium alum
Cesium alum One respect in which cesium (and rubidium) are outstanding among the alkali metals is the readiness with which it forms alums. Cesium alums are known for all of the Irivalenl cations that form alums. ... Rubidium is recovered from its ore lepidolite or pollucite. Mineral lepidolite is a lithium mica having a composition KRbLi(OH,F ...
اقرأ أكثر
Recovery of cesium from epithermal mineral deposits
The cesium alum may be recovered from the crystallizer slurry by a solid-liquid separation step. Cesium alum is water-soluble, so any washing of the alum is advantageously carried out so as to avoid re-solubilisation of the cesium alum. For example, in some embodiments, a minimal amount of washing may be carried out, and the wash water …
اقرأ أكثر
EP0131206A1
Cesium is recovered from cesium alum, CsAl(SO 4 ) 2, by an aqueous conversion and precipitation reaction using a critical stoichiometric excess of a water-soluble permanganate to form solid cesium permanganate (CsMnO 4 ) free from cesium alum. The other metal salts remain in solution, providing the final pH does not cause hydroxides of aluminum or …
اقرأ أكثر
Cesium extraction from the Taron deposit
The cesium alum is recovered by filtration and re-dissolved in warm water. The solids remaining after the re-dissolution of the alum (substantially gypsum) is filtered out and discarded. ... The cesium alum precipitation from two SO 2 reductive leaching solutions was conducted without the addition of aluminum sulfate and the results are ...
اقرأ أكثر
US Patent for Selective recovery method of vanadium and cesium …
Since cesium alum CsAl(SO 4) 2 recovered from the waste sulfuric acid vanadium catalyst may be directly utilized, or may be converted into the form of Cs 2 SO 4 through a smelting process including water leaching and then prepared into various compounds according to a purpose, the cesium alum CsAl(SO 4) 2 can be applied to various fields of ...
اقرأ أكثر